Literature DB >> 30860529

Gold(ii) in redox-switchable gold(i) catalysis.

Philipp Veit1, Carla Volkert, Christoph Förster, Vadim Ksenofontov, Steffen Schlicher, Matthias Bauer, Katja Heinze.   

Abstract

Gold(ii) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the saturated gold(i) complex is inactive. Redox-switching between gold(ii) and gold(i) turns catalytic turnover on and off.

Entities:  

Year:  2019        PMID： 30860529     DOI： 10.1039/c9cc00283a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Recent advances utilized in artificial switchable catalysis.

Authors:  Arash Ghorbani-Choghamarani; Zahra Taherinia
Journal:  RSC Adv       Date:  2022-08-19       Impact factor: 4.036

2.  Homolytic X-H Bond Cleavage at a Gold(III) Hydroxide: Insights into One-Electron Events at Gold.

Authors:  Silène Engbers; Isaac F Leach; Remco W A Havenith; Johannes E M N Klein
Journal:  Chemistry       Date:  2022-05-31       Impact factor: 5.020

3.  Triple the fun: tris(ferrocenyl)arene-based gold(i) complexes for redox-switchable catalysis.

Authors:  Axel Straube; Peter Coburger; Luis Dütsch; Evamarie Hey-Hawkins
Journal:  Chem Sci       Date:  2020-08-03       Impact factor: 9.825
  3 in total

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