Literature DB >> 30860527

Salen supported Al-O-C[triple bond, length as m-dash]P and Ga-P[double bond, length as m-dash]C[double bond, length as m-dash]O complexes.

Yanbo Mei1, Jaap E Borger, Dong-Jun Wu, Hansjörg Grützmacher.   

Abstract

The first OCP adducts of aluminium and gallium are reported. The complexes are supported by sterically encumbered salen ligands and reveal a selective binding to O and P, respectively. Their reactivity with diazaphosphenium Lewis acids and N-heterocyclic carbene Lewis bases is described, in addition to cycloaddition reactions with s-tetrazines.

Entities:  

Year:  2019        PMID： 30860527     DOI： 10.1039/c9dt00485h

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP].

Authors:  Jacob E Walley; Levi S Warring; Erik Kertész; Guocang Wang; Diane A Dickie; Zoltán Benkő; Robert J Gilliard
Journal:  Inorg Chem       Date:  2021-03-09       Impact factor: 5.165

2.  Bis-Phosphaketenes LM(PCO)2 (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

Authors:  Mahendra K Sharma; Pratima Dhawan; Christoph Helling; Christoph Wölper; Stephan Schulz
Journal:  Chemistry       Date:  2022-03-14       Impact factor: 5.020

3.  Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene.

Authors:  Daniel W N Wilson; Mauricio P Franco; William K Myers; John E McGrady; Jose M Goicoechea
Journal:  Chem Sci       Date:  2019-12-02       Impact factor: 9.825

4.  A Cyaphide Transfer Reagent.

Authors:  Daniel W N Wilson; Stephanie J Urwin; Eric S Yang; Jose M Goicoechea
Journal:  J Am Chem Soc       Date:  2021-06-30       Impact factor: 15.419
  4 in total

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