Literature DB >> 30860251

Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts.

Karthika J Kadassery1, David C Lacy.   

Abstract

Mn(i) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO)5 as a synthon in place of typical Mn(CO)5Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O-H, N-H, and even C-H bonds.

Entities:  

Year:  2019        PMID: 30860251     DOI: 10.1039/c9dt00529c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  2 in total

1.  Synthesis, structural studies, and redox chemistry of bimetallic [Mn(CO)3] and [Re(CO)3] complexes.

Authors:  Wade C Henke; Tyler A Kerr; Thomas R Sheridan; Lawrence M Henling; Michael K Takase; Victor W Day; Harry B Gray; James D Blakemore
Journal:  Dalton Trans       Date:  2021-01-18       Impact factor: 4.390

2.  Old Concepts, New Application - Additive-Free Hydrogenation of Nitriles Catalyzed by an Air Stable Alkyl Mn(I) Complex.

Authors:  Stefan Weber; Luis F Veiros; Karl Kirchner
Journal:  Adv Synth Catal       Date:  2019-10-28       Impact factor: 5.837

  2 in total

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