Understanding Anisotropic Growth of Au Penta-Twinned Nanorods by Liquid Cell Transmission Electron Microscopy.

Morphology control of anisotropic nanocrystals is important for tuning shape-dependent physicochemical properties, but the anisotropic growth mechanism remains unclear. Here we investigate the formation of the Au penta-twinned nanorod by liquid cell transmission electron microscopy. It is found that a truncated decahedron forms in the absence of cetyltrimethylammonium bromide (CTAB), whereas in the presence of CTAB, a penta-twinned nanorod forms by producing {100} facets via the reentrant groove and selectively inhibiting atom addition to {100} facets. Density functional theory simulations show that the partial relief of strain energy of the decahedron is caused by the adsorption of Br- ions. Moreover, the selective adsorption of CTAB lowers the surface energy of {100} facets, thus enhancing the nanorod growth. Our work points out the importance of the synergy of strain and surface energy, which provide an in-depth insight into the anisotropic growth of nanorods and lay foundations for the controlled synthesis of nanomaterials.