Improving the Performance and Uniformity of Carbon-Nanotube-Network-Based Photodiodes via Yttrium Oxide Coating and Decoating.

Semiconducting single-walled carbon nanotube thin films can be obtained by conjugated polymer wrapping sorting technique followed by solution deposition and can be utilized as channel materials of field-effect transistors and absorbing layers of photodiodes. However, after the deposition process, there are still polymer molecules wrapping around nanotubes, remaining between nanotubes, and remaining on the thin-film surface, which will cause large nanotube-electrode resistance and tube-tube resistance. Here, we demonstrate an yttrium oxide coating-and-decoating technique that can remove polymers only around electrodes and thus improve the performance of photodiodes without inducing new defects in the device channel. After the treatment of only the contact area, the average short-circuit current of a photodiode increases from 9.1 to 10.7 nA, whereas the average open-circuit voltage increases from 0.25 to 0.30 V. This method also improves device uniformity significantly.