Literature DB >> 30849874

Can the glass transition be explained without a growing static length scale?

Ludovic Berthier1, Giulio Biroli2, Jean-Philippe Bouchaud3, Gilles Tarjus4.   

Abstract

It was recently discovered that SWAP, a Monte Carlo algorithm that involves the exchange of pairs of particles of differing diameters, can dramatically accelerate the equilibration of simulated supercooled liquids in regimes where the normal dynamics is glassy. This spectacular effect was subsequently interpreted as direct evidence against a static, cooperative explanation of the glass transition such as the one offered by the random first-order transition (RFOT) theory. We explain the speedup induced by SWAP within the framework of the RFOT theory. We suggest that the efficiency of SWAP stems from a postponed onset of glassy dynamics. We describe this effect in terms of "crumbling metastability" and use the example of nucleation to illustrate the possibility of circumventing free-energy barriers of thermodynamic origin by a change in the local dynamical rules.

Entities:  

Year:  2019        PMID: 30849874     DOI: 10.1063/1.5086509

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  2 in total

1.  Neural Networks Reveal the Impact of the Vibrational Dynamics in the Prediction of the Long-Time Mobility of Molecular Glassformers.

Authors:  Antonio Tripodo; Gianfranco Cordella; Francesco Puosi; Marco Malvaldi; Dino Leporini
Journal:  Int J Mol Sci       Date:  2022-08-18       Impact factor: 6.208

2.  Revisiting the concept of activation in supercooled liquids.

Authors:  Marco Baity-Jesi; Giulio Biroli; David R Reichman
Journal:  Eur Phys J E Soft Matter       Date:  2021-06-14       Impact factor: 1.890

  2 in total

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