| Literature DB >> 30848273 |
Yan-Ling Li1, Zhao-Yang Wang, Xiao-Hong Ma, Peng Luo, Chen-Xia Du, Shuang-Quan Zang.
Abstract
The synthesis of atom-precise analogues of homometallic nanoclusters remains a great challenge. Herein we report the first pair of atom-precise copper/silver-thiolate halide cluster analogues, namely [Cu17/Ag17I3S(C2B10H10S2)6(CH3CN)11] (Cu17 and Ag17), obtained by bottom-up self-assembly and complete-metal-exchange-induced cluster-to-cluster transformation, respectively. The differences in optical absorption and emission of these analogues were fully elucidated by experimental and theoretical methods.Entities:
Year: 2019 PMID: 30848273 DOI: 10.1039/c9nr01058k
Source DB: PubMed Journal: Nanoscale ISSN: 2040-3364 Impact factor: 7.790