Literature DB >> 30834905

Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds.

Chao Yan1, Xiujuan Qi, Kangcai Wang, Yunhe Jin, Guangbin Cheng, Tianlin Liu, Hongwei Yang, Qinghua Zhang.   

Abstract

A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7.

Entities:  

Year:  2019        PMID: 30834905     DOI: 10.1039/c8cc10178g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Noncovalent Interactions and Crystal Structure Prediction of Energetic Materials.

Authors:  Yan Liu; Chongwei An; Ning Liu; Minchang Wang; Baoyun Ye; Dongjie Liao
Journal:  Molecules       Date:  2022-06-10       Impact factor: 4.927

  1 in total

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