Literature DB >> 30821980

Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination.

Sailu Munnuri1, Raghunath Reddy Anugu1, John R Falck1.   

Abstract

Cu(II)-mediated direct NH2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh2 catalysts and, in some instances, display important differences with comparable Rh2- and Fe-supported reactions.

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Year:  2019        PMID: 30821980     DOI: 10.1021/acs.orglett.9b00586

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Site-selective amination and/or nitrilation via metal-free C(sp2)-C(sp3) cleavage of benzylic and allylic alcohols.

Authors:  Raghunath Reddy Anugu; John R Falck
Journal:  Chem Sci       Date:  2022-04-05       Impact factor: 9.969

Review 2.  The advent of electrophilic hydroxylamine-derived reagents for the direct preparation of unprotected amines.

Authors:  Valentina C M Gasser; Szabolcs Makai; Bill Morandi
Journal:  Chem Commun (Camb)       Date:  2022-09-08       Impact factor: 6.065

3.  Aziridine synthesis by coupling amines and alkenes via an electrogenerated dication.

Authors:  Dylan E Holst; Diana J Wang; Min Ji Kim; Ilia A Guzei; Zachary K Wickens
Journal:  Nature       Date:  2021-06-22       Impact factor: 69.504

  3 in total

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