| Literature DB >> 30807672 |
Masanori Shigeno1, Kazutoshi Hayashi1, Kanako Nozawa-Kumada1, Yoshinori Kondo1.
Abstract
The organic superbase tBu-P4 catalyzes methoxy-alkoxy exchange reactions on (hetero)arenes with alcohols. The catalytic reaction proceeded efficiently with electron-deficient methoxy(hetero)arenes as well as with a variety of alcohols, including 3-amino-1-propanol, β-citronellol, menthol, and cholesterol. An intramolecular version of this reaction furnished six- and seven-membered ring compounds.Entities:
Keywords: alcohols; aromatic substitution; methoxyarenes; organocatalysis; phosphazenes
Year: 2019 PMID： 30807672 DOI： 10.1002/chem.201900498
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236