Literature DB >> 30806394

Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes.

Priyabrata Ghana1, Franziska D van Krüchten, Thomas P Spaniol, Jan van Leusen, Paul Kögerler, Jun Okuda.   

Abstract

By using a triaryl-Tren ligated titanium dinitrogen complex, K2[{(Xy-N3N)Ti}2(μ2-N2)] (3), prepared by two-electron reduction of [TiCl(Xy-N3N)] (1-Cl) under N2 atmosphere, catalytic fixation of molecular nitrogen to form tris(trimethylsilyl)amine was achieved under ambient conditions with a turnover number (TON) of up to 16.5 per titanium atom.

Entities:  

Year:  2019        PMID： 30806394     DOI： 10.1039/c8cc09742a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Examining the Generality of Metal-Ligand Cooperativity Across a Series of First-Row Transition Metals: Capture, Bond Activation, and Stabilization.

Authors:  John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  Inorg Chem       Date:  2020-06-18       Impact factor: 5.165

2.  Evaluating Metal Ion Identity on Catalytic Silylation of Dinitrogen Using a Series of Trimetallic Complexes.

Authors:  Mary C Eaton; Brian J Knight; Vincent J Catalano; Leslie J Murray
Journal:  Eur J Inorg Chem       Date:  2020-02-21       Impact factor: 2.524

3.  Reduced Arene Complexes of Hafnium Supported by a Triamidoamine Ligand.

Authors:  Priyabrata Ghana; Sebastian Schrader; Thayalan Rajeshkumar; Thomas P Spaniol; Ulli Englert; Laurent Maron; Jun Okuda
Journal:  Angew Chem Int Ed Engl       Date:  2021-05-07       Impact factor: 15.336

4.  Synthesis and Reactivity of Manganese Complexes Bearing Anionic PNP- and PCP-Type Pincer Ligands toward Nitrogen Fixation.

Authors:  Shogo Kuriyama; Shenglan Wei; Takeru Kato; Yoshiaki Nishibayashi
Journal:  Molecules       Date:  2022-04-06       Impact factor: 4.411

5.  Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions.

Authors:  Estefanía Del Horno; Jesús Jover; Miguel Mena; Adrián Pérez-Redondo; Carlos Yélamos
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-11       Impact factor: 16.823
  5 in total

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