Literature DB >> 30803108

A Size-Flexible Organometallic Box for the Encapsulation of Fullerenes.

Victor Martínez-Agramunt1, Tobias Eder1,2, Heidar Darmandeh1,3, Gregorio Guisado-Barrios1, Eduardo Peris1.   

Abstract

A palladium-cornered molecular square with four pyrene-bis(imidazolylidene) bridging ligands is reported. This metallo-polygon can encapsulate C60 and C70 . The X-ray diffraction structures of the empty cage as well as the cages complexed with both fullerenes are described. The fullerene encapsulation produces perturbations in the structural parameters of the metallo-square, showing that it can adjust the shape of its cavity to the size of each fullerene.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  N-heterocyclic carbenes; fullerenes; host-guest systems; palladium; self-assembly

Year:  2019        PMID： 30803108     DOI： 10.1002/anie.201901586

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Gram-scale synthesis of a covalent nanocage that preserves the redox properties of encapsulated fullerenes.

Authors:  Daniel A Rothschild; William P Kopcha; Aaron Tran; Jianyuan Zhang; Mark C Lipke
Journal:  Chem Sci       Date:  2022-04-13       Impact factor: 9.969

2.  Porphyrin-based systems containing polyaromatic fragments: decoupling the synergistic effects in aromatic-porphyrin-fullerene systems.

Authors:  Sergio Ferrero; Héctor Barbero; Daniel Miguel; Raúl García-Rodríguez; Celedonio M Álvarez
Journal:  RSC Adv       Date:  2020-10-01       Impact factor: 4.036

3.  Pd(II) Coordination Sphere Engineering: Pyridine Cages, Quinoline Bowls, and Heteroleptic Pills Binding One or Two Fullerenes.

Authors:  Bin Chen; Julian J Holstein; Shinnosuke Horiuchi; Wolf G Hiller; Guido H Clever
Journal:  J Am Chem Soc       Date:  2019-05-22       Impact factor: 15.419

4.  Cooperativity of steric bulk and H-bonding in coordination sphere engineering: heteroleptic PdII cages and bowls by design.

Authors:  Bin Chen; Julian J Holstein; André Platzek; Laura Schneider; Kai Wu; Guido H Clever
Journal:  Chem Sci       Date:  2022-01-17       Impact factor: 9.825

5.  Subphthalocyanine capsules: molecular reactors for photoredox transformations of fullerenes.

Authors:  Marta Moreno-Simoni; Tomás Torres; Gema de la Torre
Journal:  Chem Sci       Date:  2022-07-19       Impact factor: 9.969

6.  Synthesis of N-Heterocyclic Carbenes and Their Complexes by Chloronium Ion Abstraction from 2-Chloroazolium Salts Using Electron-Rich Phosphines.

Authors:  Matthias D Böhme; Tobias Eder; Maike B Röthel; Patrick D Dutschke; Lukas F B Wilm; F Ekkehardt Hahn; Fabian Dielmann
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-17       Impact factor: 16.823

7.  Single-Walled Carbon Nanotubes Encapsulated within Metallacycles.

Authors:  Alejandro López-Moreno; Susana Ibáñez; Sara Moreno-Da Silva; Luisa Ruiz-González; Natalia Martín Sabanés; Eduardo Peris; Emilio M Pérez
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-18       Impact factor: 16.823
  7 in total

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