| Literature DB >> 30801592 |
Sergii I Shylin1, Mariia V Pavliuk, Luca D'Amario, Fikret Mamedov, Jacinto Sá, Gustav Berggren, Igor O Fritsky.
Abstract
A water-stable FeIV clathrochelate complex catalyses fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s-1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.Entities:
Year: 2019 PMID: 30801592 DOI: 10.1039/c9cc00229d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222