Literature DB >> 30785740

Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations.

Fei Jia1,2, Henrik Hupatz1, Liu-Pan Yang2, Hendrik V Schröder1, Dong-Hao Li2, Shan Xin2, Dieter Lentz3, Felix Witte1, Xiaojiang Xie2, Beate Paulus1, Christoph A Schalley1, Wei Jiang2.   

Abstract

We report a quite flexible naphthol-based cage (so-called "naphthocage") which adopts a self-inclusion conformation in its free state and is able to bind singly charged organic cations extremely strongly ( Ka > 107 M-1). Ion-selective electrodes prepared with this naphthocage show a super-Nernstian response to acetylcholine. In addition, the highly stable complex (1010 M-1) between ferrocenium and the naphthocage can be switched electrochemically, which lays a basis for its application in stimuli-responsive materials.

Entities:  

Year:  2019        PMID： 30785740     DOI： 10.1021/jacs.9b00445

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

Review 1.  Purely Covalent Molecular Cages and Containers for Guest Encapsulation.

Authors:  Giovanni Montà-González; Félix Sancenón; Ramón Martínez-Máñez; Vicente Martí-Centelles
Journal:  Chem Rev       Date:  2022-07-22       Impact factor: 72.087

Review 2.  Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.

Authors:  Charlie T McTernan; Jack A Davies; Jonathan R Nitschke
Journal:  Chem Rev       Date:  2022-04-18       Impact factor: 72.087

3.  Calix[2]naphth[2]arene: A Class of Naphthalene-Phenol Hybrid Macrocyclic Hosts.

Authors:  Rocco Del Regno; Paolo Della Sala; Aldo Spinella; Carmen Talotta; Dalila Iannone; Silvano Geremia; Neal Hickey; Placido Neri; Carmine Gaeta
Journal:  Org Lett       Date:  2020-07-20       Impact factor: 6.005

4.  Molecular Recognition in an Aqueous Medium Using Water-Soluble Prismarene Hosts.

Authors:  Rocco Del Regno; Giuseppina D G Santonoceta; Paolo Della Sala; Margherita De Rosa; Annunziata Soriente; Carmen Talotta; Aldo Spinella; Placido Neri; Carmelo Sgarlata; Carmine Gaeta
Journal:  Org Lett       Date:  2022-04-07       Impact factor: 6.072

5.  An intramolecularly self-templated synthesis of macrocycles: self-filling effects on the formation of prismarenes.

Authors:  Paolo Della Sala; Rocco Del Regno; Luca Di Marino; Carmela Calabrese; Carmine Palo; Carmen Talotta; Silvano Geremia; Neal Hickey; Amedeo Capobianco; Placido Neri; Carmine Gaeta
Journal:  Chem Sci       Date:  2021-06-03       Impact factor: 9.825
  5 in total

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