| Literature DB >> 30768277 |
Minghe Sun1, Jia-Feng Chen2, Shufeng Chen1, Changkun Li2.
Abstract
A highly enantioselective cobalt-catalyzed reverse prenylation of β-ketoester with tertiary allylic carbonate to construct vicinal all-carbon quaternary carbon centers has been developed. By using the cobalt/( S, S)Ph-BPE complex generated in situ with zinc reduction, excellent branched to linear selectivity (>20:1) and up to 92% ee have been obtained.Entities:
Year: 2019 PMID： 30768277 DOI： 10.1021/acs.orglett.8b04030
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005