| Literature DB >> 30767387 |
Haiyong Wang1,2,3,4, Changhui Zhu1,2,3,4, Qiying Liu1,2,3,5, Jin Tan1,2,3, Chenguang Wang1,2,3, Zheng Liang1,2,3, Longlong Ma1,2,3.
Abstract
The high-value-added chemicals hydroxyacetone (HA) and 1-hydroxy-2-butanone (HB) were produced from agricultural waste over a Ni3 Sn4 -SnOx catalyst. The Sn-Ni intermetallic compound and SnOx acted as the active sites for HA and HB production by selectively cleaving the target C-C and C-O bonds. Approximately 70 % of the total HA and HB yield was obtained by selective hydrogenolysis of cellulose. This strategy expands the application of cellulose towards renewable production of high-value C3 and C4 keto-alcohols from cellulosic biomass.Entities:
Keywords: biomass; cellulose; hydroxyacetone; intermetallic; keto-alcohols
Year: 2019 PMID： 30767387 DOI： 10.1002/cssc.201900172
Source DB: PubMed Journal: ChemSusChem ISSN： 1864-5631 Impact factor: 8.928