Literature DB >> 30762068

Solvent-free anhydrous Li+, Na+ and K+ salts of [B(3,5-(CF3)2C6H3)4]-, [BArF4]-. Improved synthesis and solid-state structures.

Antonio J Martínez-Martínez1, Andrew S Weller.   

Abstract

A modified, convenient, preparation of solvent-free, anhydrous, Li+, Na+ and K+ salts of the ubiquitous [BArF4]- anion is reported, that involves a simple additional recrystallisation step. Anhydrous Na[BArF4], K[BArF4], and [Li(H2O)][BArF4], were characterised by single-crystal X-ray diffraction.

Entities:  

Year:  2019        PMID： 30762068     DOI： 10.1039/c9dt00235a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

1.  Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex.

Authors:  Amy E Kynman; Samantha Lau; Sean O Dowd; Tobias Krämer; Adrian B Chaplin
Journal:  Eur J Inorg Chem       Date:  2020-10-20       Impact factor: 2.524

2.  Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H2 and D2.

Authors:  Oliver P E Townrow; Simon B Duckett; Andrew S Weller; Jose M Goicoechea
Journal:  Chem Sci       Date:  2022-06-09       Impact factor: 9.969

3.  Mechanistic Investigations on Hydrogenation, Isomerization and Hydrosilylation Reactions Mediated by a Germyl-Rhodium System.

Authors:  Sonia Bajo; Cyril A Theulier; Jesús Campos
Journal:  ChemCatChem       Date:  2022-05-31       Impact factor: 5.497
  3 in total

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