Single Particle Electrochemistry of Collision.

A novel electrochemistry method using stochastic collision of particles at microelectrode to study their performance in single-particle scale has obtained remarkable development in recent years. This convenient and swift analytical method, which can be called "nanoimpact," is focused on the electrochemical process of the single particle rather than in complex ensemble systems. Many researchers have applied this nanoimpact method to investigate various kinds of materials in many research fields, including sensing, electrochemical catalysis, and energy storage. However, the ways how they utilize the method are quite different and the key points can be classified into four sorts: sensing particles at ultralow concentration, theory optimization, kinetics of mediated catalytic reaction, and redox electrochemistry of the particles. This review gives a brief overview of the development of the nanoimpact method from the four aspects in a new perspective.