Literature DB >> 30734564

Synthesis, Regioselective Bromination, and Functionalization of Coronene Tetracarboxydiimide.

Taifeng Liu1,2, Yongchao Ge1, Baolai Sun1, Brandon Fowler2, Hexing Li1, Colin Nuckolls1,2, Shengxiong Xiao1.   

Abstract

A new method for the effective synthesis of coronene tetracarboxydiimide (CDI) was developed by utilizing inexpensive and nontoxic potassium vinyltrifluoroborate. Controllable brominations of CDI were accomplished to yield CDI mono-, di-, tri-, and tetra-bromides, which could be used as synthon and functionalized by aromatic nucleophilic substitution and the Sonogashira coupling reaction.

Entities:  

Year:  2019        PMID： 30734564     DOI： 10.1021/acs.joc.8b03129

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Pseudo-atomic orbital behavior in graphene nanoribbons with four-membered rings.

Authors:  Peter H Jacobse; Zexin Jin; Jingwei Jiang; Samuel Peurifoy; Ziqin Yue; Ziyi Wang; Daniel J Rizzo; Steven G Louie; Colin Nuckolls; Michael F Crommie
Journal:  Sci Adv       Date:  2021-12-22       Impact factor: 14.136

Review 2.  Diels-Alder Cycloaddition to the Bay Region of Perylene and Its Derivatives as an Attractive Strategy for PAH Core Expansion: Theoretical and Practical Aspects.

Authors:  Aneta Kurpanik; Marek Matussek; Piotr Lodowski; Grażyna Szafraniec-Gorol; Michał Krompiec; Stanisław Krompiec
Journal:  Molecules       Date:  2020-11-17       Impact factor: 4.411
  2 in total

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