Literature DB >> 30729960

Halogen bonding effects on the outcome of reactions at metal centres.

Lucas Carreras1, Jordi Benet-Buchholz, Antonio Franconetti, Antonio Frontera, Piet W N M van Leeuwen, Anton Vidal-Ferran.   

Abstract

Key findings regarding the effects of ligand preorganisation via halogen bonding on the outcome of reactions at rhodium are reported. An unprecedented halogen bonding-mediated oxidative addition of CAr-I bonds to rhodium with efficient formation of cyclometallated species deserves special mention.

Entities:  

Year:  2019        PMID： 30729960     DOI： 10.1039/c8cc08884e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Metal Centers as Nucleophiles: Oxymoron of Halogen Bond-Involving Crystal Engineering.

Authors:  Daniil M Ivanov; Nadezhda A Bokach; Vadim Yu Kukushkin; Antonio Frontera
Journal:  Chemistry       Date:  2021-10-29       Impact factor: 5.020

2.  Activation of a Metal-Halogen Bond by Halogen Bonding.

Authors:  Julian Wolf; Florian Huber; Nikita Erochok; Flemming Heinen; Vincent Guérin; Claude Y Legault; Stefan F Kirsch; Stefan M Huber
Journal:  Angew Chem Int Ed Engl       Date:  2020-07-10       Impact factor: 15.336
  2 in total

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