Detailed study of water radiolysis-based degradation of chloroorganic pollutants in aqueous solutions.

Water radiolysis-induced destruction, dechlorination and mineralization of harmful chlorophenols, i.e., 2,4,6-trichlorophenol (2,4,6-tCPH), 4-chlorophenol (4-CPH) and 4-chlorocatechol (4-CC), using radioactive Co-60 have been investigated as individual and combination methods (2,4,6-tCPH+4-CPH+4-CC) with an initial concentration of 100 μM of each pollutant. The kinetic efficiencies of chlorophenol destruction were compared. The individual destruction percentages of 2,4,6-tCPH, 4-CPH and 4-CC reached at least 99% with absorbed doses (D99%) of 1.44, 1.73 and 1.85 kGy, respectively. Substantially higher absorbed doses were required to destroy each chlorophenol when they were all present in the treated. HCO3- anions inhibit the elimination efficiency of chlorophenols. The effects of S2O82- anions, N2O and N2 on destruction and mineralization were elaborated. O2 was crucial for the mineralization. Except for the γ-ray/N2 system, full mineralization was achieved for both individual and combined chlorophenols. The results indicate that hydrated electrons (eaq-) do not have a direct effect on the destruction of these chlorophenols. The study main goals were to show the successful application of ionizing radiation as a useful tool for environmental remediation, to continue scientific research on ionizing radiation as an advanced oxidation technology (AOT) and to provide a new, economic, practical and efficient solution to remove pollutants from aqueous media.