Literature DB >> 30690838

Total Synthesis of Actinorhodin.

Mamiko Ninomiya1, Yoshio Ando1, Fumitaka Kudo1, Ken Ohmori1, Keisuke Suzuki1.   

Abstract

The enantioselective total synthesis of actinorhodin (1) is described. The synthesis features 1) dual benzyne reactions en route to the monomer, 2) the trans-selective installation of the side chain, and 3) a regioselective oxidative dimerization.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  dimerization; natural products; pigments; pyranonaphthoquinones; total synthesis

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Substances：

Year:  2019        PMID： 30690838     DOI： 10.1002/anie.201814172

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  2 in total

Review 1.  Unraveling Plant Natural Chemical Diversity for Drug Discovery Purposes.

Authors:  Emmanuelle Lautié; Olivier Russo; Pierre Ducrot; Jean A Boutin
Journal:  Front Pharmacol       Date:  2020-04-07       Impact factor: 5.810

2.  Total Synthesis of 6-Deoxydihydrokalafungin, a Key Biosynthetic Precursor of Actinorhodin, and Its Epimer.

Authors:  Takuya Kumamoto; Mika Kainuma; Azusa Takahashi; Yoshika Matsuo; Kazuaki Katakawa; Takaaki Taguchi; Koji Ichinose
Journal:  Molecules       Date:  2021-10-22       Impact factor: 4.411
  2 in total

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