Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes.

We report the use of vinyl ethylene carbonate as a new solid electrolyte interface (SEI)-forming additive for Li-metal anodes in carbonate-based electrolyte, which has the advantages of both good storage performance and low price. Compared to the SEI formed in vinyl ethylene carbonate-free electrolyte, the SEI film formed in 10% vinyl ethylene carbonate electrolyte contains a higher relative content of polycarbonate species and a greater amount of decomposition products of LiPF6 salt. Both components are expected to have positive effects on the passivation of Li-metal surface and the accommodation of volume changes of anode during cycling. Scanning electron microscopy images and COMSOL numerical simulation results further confirm that uniform Li deposition morphology can be achieved in the presence of vinyl ethylene carbonate additive. When cycling at the current density of 0.25 mA cm-2 with a cycling capacity of 1.0 mAh cm-2, the vinyl ethylene carbonate-contained Li-Cu cell exhibits a long life span of 816 h (100 cycles) and a relatively high Coulombic efficiency of 93.2%.