Literature DB >> 30638369

Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions.

Jian-Hao Huang1, Cong-Cong Jin1, Pei-Li Xu1, Pifu Gong2, Zheshuai Lin2, Jian-Wen Cheng1, Guo-Yu Yang3.   

Abstract

A new noncentrosymmetric mixed-alkaline borate, Li2CsB7O10(OH)4 (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B7O12(OH)4]7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH2PO4), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.

Entities:  

Year:  2019        PMID： 30638369     DOI： 10.1021/acs.inorgchem.8b03495

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  SrTi(IO3)6·2H2O and SrSn(IO3)6: distinct arrangements of lone pair electrons leading to large birefringences.

Authors:  Kaitong Liu; Jian Han; Junben Huang; Zhonglei Wei; Zhihua Yang; Shilie Pan
Journal:  RSC Adv       Date:  2021-03-10       Impact factor: 3.361

2.  Two New Nonaborates with {B9} Cluster Open-Frameworks and Short Cutoff Edges.

Authors:  Chong-An Chen; Guo-Yu Yang
Journal:  Molecules       Date:  2022-08-18       Impact factor: 4.927
  2 in total

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