Controlled Manipulation of Metal-Organic Framework Layers to Nanometer Precision Inside Large Mesochannels of Ordered Mesoporous Silica for Enhanced Removal of Bisphenol A from Water.

Considerable attention has been paid on the design of hierarchical porous metal-organic framework (MOF) composites, which not only enhances the performance but also broadens the applications of MOFs. So far, controlled manipulation of nanometer-thick MOF layers in ordered mesochannels, while retaining their respective intrinsic properties, is still a main challenge because of the difficulty of growing MOFs in confined space. Herein, using a step-by-step coordination method, the formation of a hierarchical micro-mesoporous hybrid with a wall (channel wall and coating layer) thickness of up to 8.0 nm and open pore size down to 7.7 nm has been achieved based on large mesoporous SBA-15, and the wall thickness with nanometer precision can be controlled by adjusting the growth cycles of zeolite imidazolate framework-8 (ZIF-8) coating layers. Compared to pure ZIF-8, the obtained ZIF-8@SBA-15 composites showed more than 2-fold enhancement in adsorption capacity and approximately 20-fold improvement in the adsorption rate constant for bisphenol A in water, which could be ascribed to the synergistic effects of the high adsorption ability from ZIF-8 and the fast diffusion property from SBA-15. More importantly, the degraded ZIF-8@SBA-15 composite can be completely restored by a simple immersion into 2-methylimidazole solution. The easy restorability and good reusability further enable ZIF-8@SBA-15 as a promising adsorbent for effectively removing organic contaminants from water.