Literature DB >> 30607431

Enzyme-like substrate-selectivity in C-H oxidation enabled by recognition.

Giorgio Olivo1, Giorgio Capocasa, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas.   

Abstract

Substrate-selectivity stemming from recognition is a key feature of enzymes that has been seldom observed in artificial catalysts. Herein, we report a recognition-driven, substrate-selective C-H oxidation that inverts the intrinsic reactivity of the competing C-H bonds. Analysis of this selectivity highlights an unexpectedly high reactivity enhancement imparted by intramolecularity.

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Year:  2019        PMID： 30607431     DOI： 10.1039/c8cc09328h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Electric Fields in Catalysis: From Enzymes to Molecular Catalysts.

Authors:  Nadia G Léonard; Rakia Dhaoui; Teera Chantarojsiri; Jenny Y Yang
Journal:  ACS Catal       Date:  2021-08-18       Impact factor: 13.700

2.  Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C-H oxidation.

Authors:  Federico Frateloreto; Giorgio Capocasa; Giorgio Olivo; Karim Abdel Hady; Carla Sappino; Marika Di Berto Mancini; Stefano Levi Mortera; Osvaldo Lanzalunga; Stefano Di Stefano
Journal:  RSC Adv       Date:  2020-12-24       Impact factor: 3.361

3.  Remote Amino Acid Recognition Enables Effective Hydrogen Peroxide Activation at a Manganese Oxidation Catalyst.

Authors:  Laia Vicens; Giorgio Olivo; Miquel Costas
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-23       Impact factor: 16.823

Review 4.  Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.

Authors:  Luca Capaldo; Davide Ravelli; Maurizio Fagnoni
Journal:  Chem Rev       Date:  2021-08-06       Impact factor: 60.622
  4 in total

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