Literature DB >> 30565600

Rhodium(iii) vs. cobalt(iii): a mechanistically distinct three-component C-H bond addition cascade using a Cp*RhIII catalyst.

Ruirui Li1, Cheng-Wei Ju, Dongbing Zhao.   

Abstract

Three-component C-H bond additions across two different coupling partners remain underdeveloped. Herein, we report the first three-component RhIII-catalyzed C-H bond additions to a wide range of dienes and aldehydes. Our method constitutes a complementary access with Ellman's CoIII-catalytic system to homoallylic alcohols.

Entities:  

Year:  2019        PMID： 30565600     DOI： 10.1039/c8cc08792j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Synthesis of Homoallylic Alcohols with Acyclic Quaternary Centers through CoIII -Catalyzed Three-Component C-H Bond Addition to Internally Substituted Dienes and Carbonyls.

Authors:  Sun Dongbang; Zican Shen; Jonathan A Ellman
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-01       Impact factor: 15.336

Review 2.  C-H bond activation and sequential addition to two different coupling partners: a versatile approach to molecular complexity.

Authors:  Daniel S Brandes; Jonathan A Ellman
Journal:  Chem Soc Rev       Date:  2022-08-01       Impact factor: 60.615

3.  Stereoselective Synthesis of Allenyl Alcohols by Cobalt(III)-Catalyzed Sequential C-H Bond Addition to 1,3-Enynes and Aldehydes.

Authors:  Chaofan Xu; Joseph P Tassone; Brandon Q Mercado; Jonathan A Ellman
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-29       Impact factor: 16.823

4.  Nickel/Brønsted Acid-Catalyzed Chemo- and Enantioselective Intermolecular Hydroamination of Conjugated Dienes.

Authors:  Jiao Long; Peng Wang; Wang Wang; Yuqiang Li; Guoyin Yin
Journal:  iScience       Date:  2019-11-11

5.  Synthesis of Nitrile Bearing Acyclic Quaternary Centers through Co(III)-Catalyzed Sequential C-H Bond Addition to Dienes and N-Cyanosuccinimide.

Authors:  Sun Dongbang; Jonathan A Ellman
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-23       Impact factor: 15.336
  5 in total

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