Literature DB >> 30565593

A mono-metallic Pd(ii)-cage featuring two different polar binding sites.

Luis Escobar1, David Villarón, Eduardo C Escudero-Adán, Pablo Ballester.   

Abstract

The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(ii)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism for guest exchange in the cage complexes is proposed.

Entities:  

Year:  2019        PMID： 30565593     DOI： 10.1039/c8cc09195a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Recognition with metallo cavitands.

Authors:  Faiz-Ur Rahman; Yong-Sheng Li; Ioannis D Petsalakis; Giannoula Theodorakopoulos; Julius Rebek; Yang Yu
Journal:  Proc Natl Acad Sci U S A       Date:  2019-08-19       Impact factor: 11.205

2.  Synthesis, X-ray Characterization and Density Functional Theory (DFT) Studies of Two Polymorphs of the α,α,α,α, Isomer of Tetra-p-Iodophenyl Tetramethyl Calix[4]pyrrole: On the Importance of Halogen Bonds.

Authors:  Dragoș Dăbuleanu; Antonio Bauzá; Joaquín Ortega-Castro; Eduardo C Escudero-Adán; Pablo Ballester; Antonio Frontera
Journal:  Molecules       Date:  2020-01-10       Impact factor: 4.411
  2 in total

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