Literature DB >> 30562466

Iridium-Catalyzed Hydrosilylation of Unactivated Alkenes: Scope and Application to Late-Stage Functionalization.

Xingze Xie1, Xueyan Zhang1, Haoyu Yang1, Xin Ji1, Jianing Li1, Shengtao Ding1.   

Abstract

Highly efficient and general Ir-catalyzed hydrosilylation of unactivated alkenes with excellent anti-Markovnikov regioselectivity was described. A broad scope of hydrosilylated products were synthesized economically and conveniently from commercially or naturally available compounds, which provides versatile valuable precursors for organic and medicinal studies.

Entities:  

Year:  2018        PMID： 30562466     DOI： 10.1021/acs.joc.8b02838

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Ga+-catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions.

Authors:  Antoine Barthélemy; Kim Glootz; Harald Scherer; Annaleah Hanske; Ingo Krossing
Journal:  Chem Sci       Date:  2021-11-23       Impact factor: 9.825

2.  A library of new bifunctional alkenes obtained by a highly regiodivergent silylation of 1,5-hexadiene.

Authors:  Rafał Januszewski; Bartosz Orwat; Jan Merna; Ireneusz Kownacki
Journal:  RSC Adv       Date:  2021-12-07       Impact factor: 4.036

Review 3.  The Use of the Thiol-Ene Addition Click Reaction in the Chemistry of Organosilicon Compounds: An Alternative or a Supplement to the Classical Hydrosilylation?

Authors:  Ilya Krizhanovskiy; Maxim Temnikov; Yuriy Kononevich; Anton Anisimov; Fedor Drozdov; Aziz Muzafarov
Journal:  Polymers (Basel)       Date:  2022-07-29       Impact factor: 4.967
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.