Literature DB >> 30543210

Li(NH3)B3H8: a new ionic liquid octahydrotriborate.

Xiongfei Zheng1, Yanjing Yang, Mengxuan Li, Fengqi Zhao, Qinfen Gu, Xiaohua Ma, Yanhui Guo.   

Abstract

We report a strategy of using small cations to construct ionic liquid octahydrotriborate. The novel liquid Li(NH3)B3H8, prepared by a facile reaction of NH4B3H8 with LiH, froze below -33.4 °C and crystallized into a monoclinic unit cell with lattice parameters of a = 8.813(1) Å, b = 8.8626(1) Å, c = 8.2076(1) Å, and β = 110.1046(5)°, providing a promising functional liquid octahydrotriborate with the highest B3H8- content and lowest freezing temperature.

Entities:  

Year:  2019        PMID： 30543210     DOI： 10.1039/c8cc08300b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Interplay between the Reorientational Dynamics of the B3H8 - Anion and the Structure in KB3H8.

Authors:  M S Andersson; J B Grinderslev; X-M Chen; X Chen; U Häussermann; W Zhou; T R Jensen; M Karlsson; T J Udovic
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2021-02-16       Impact factor: 4.126

2.  Nucleophilic Substitution Reactions in the [B3H8]- Anion in the Presence of Lewis Acids.

Authors:  Alexandra T Shulyak; Evgeniy O Bortnikov; Nikita A Selivanov; Mikhail S Grigoriev; Alexey S Kubasov; Andrey P Zhdanov; Alexander Y Bykov; Konstantin Y Zhizhin; Nikolai T Kuznetsov
Journal:  Molecules       Date:  2022-01-24       Impact factor: 4.411
  2 in total

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