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Literature DB >> 30537262

Reduction of Carbon Oxides by an Acyclic Silylene: Reductive Coupling of CO.

Andrey V Protchenko¹, Petra Vasko¹, Dinh Cao Huan Do¹, Jamie Hicks¹, M Ángeles Fuentes¹, Cameron Jones², Simon Aldridge¹.

Abstract

Reactions of a boryl-substituted acyclic silylene with carbon dioxide and monoxide are reported. The former proceeds through oxygen atom abstraction, generating CO (with rearrangement of the putative silanone product through silyl-group transfer). The latter is characterized by reductive coupling of CO to give an ethynediolate fragment, which undergoes formal insertion into the Si-B bond. The net conversion of carbon dioxide with two equivalents of silylene offers a route for the three-electron reduction of CO2 to [C2 O2 ]2- .

Entities: Chemical

Keywords: boryl groups; carbon monoxide; reduction; silicon; silylene

Year: 2019 PMID： 30537262 DOI： 10.1002/anie.201812675

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

10 in total

1. CO reductive oligomerization by a divalent thulium complex and CO₂-induced functionalization.

Authors: Thomas Simler; Karl N McCabe; Laurent Maron; Grégory Nocton
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2. Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation.

Authors: K Yuvaraj; Iskander Douair; Dafydd D L Jones; Laurent Maron; Cameron Jones
Journal: Chem Sci Date: 2020-03-06 Impact factor: 9.825

3. Reductive Dimerization of CO by a Na/Mg(I) Diamide.

Authors: Han-Ying Liu; Ryan J Schwamm; Samuel E Neale; Michael S Hill; Claire L McMullin; Mary F Mahon
Journal: J Am Chem Soc Date: 2021-10-15 Impact factor: 15.419

4. Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation.

Authors: Joschua Helmer; Olli J Pakkanen; Chris Gendy; Alexander Hepp; Heikki M Tuononen; Felicitas Lips
Journal: Chem Commun (Camb) Date: 2022-03-10 Impact factor: 6.222

Reduction of Carbon Oxides by an Acyclic Silylene: Reductive Coupling of CO.

1. CO reductive oligomerization by a divalent thulium complex and CO₂-induced functionalization.

2. Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation.

3. Reductive Dimerization of CO by a Na/Mg(I) Diamide.

4. Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation.

5. DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds.

6. Coordination and Homologation of CO at Al(I): Mechanism and Chain Growth, Branching, Isomerization, and Reduction.

Review 7. Molecular Catalysts for the Reductive Homocoupling of CO₂ towards C₂₊ Compounds.

8. Photo-Induced Ruthenium-Catalyzed Double Remote C(sp² )-H / C(sp³ )-H Functionalizations by Radical Relay.

Review 9. Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis.

10. Synthesis and Reactivity of Bis(silylene)-Coordinated Calcium and Divalent Lanthanide Complexes.

Review 7. Molecular Catalysts for the Reductive Homocoupling of CO2 towards C2+ Compounds.

Review 9. Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis.

Review 7. Molecular Catalysts for the Reductive Homocoupling of CO₂ towards C₂₊ Compounds.