Literature DB >> 30533578

Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex.

Anaïs Pitto-Barry1, Nicolas P E Barry1.   

Abstract

A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO(g). Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule.

Entities:  

Year:  2018        PMID： 30533578      PMCID： PMC6275942          DOI： 10.1021/acsomega.8b02154

Source DB:  PubMed          Journal:  ACS Omega        ISSN： 2470-1343


  23 in total

1.  Fuel cells: principles, types, fuels, and applications.

Authors:  L Carrette; K A Friedrich; U Stimming
Journal:  Chemphyschem       Date:  2000-12-15       Impact factor: 3.102

2.  New Class of Hybrid Materials for Detection, Capture, and "On-Demand" Release of Carbon Monoxide.

Authors:  Anaïs Pitto-Barry; Alexandru Lupan; Christopher Ellingford; Amr A A Attia; Nicolas P E Barry
Journal:  ACS Appl Mater Interfaces       Date:  2018-04-13       Impact factor: 9.229

3.  Silacarboxylic acids as efficient carbon monoxide releasing molecules: synthesis and application in palladium-catalyzed carbonylation reactions.

Authors:  Stig D Friis; Rolf H Taaning; Anders T Lindhardt; Troels Skrydstrup
Journal:  J Am Chem Soc       Date:  2011-10-24       Impact factor: 15.419

4.  An N,N'-diamidocarbene: studies in C-H insertion, reversible carbonylation, and transition-metal coordination chemistry.

Authors:  Todd W Hudnall; Christopher W Bielawski
Journal:  J Am Chem Soc       Date:  2009-11-11       Impact factor: 15.419

5.  Self-accelerating CO sorption in a soft nanoporous crystal.

Authors:  Hiroshi Sato; Wataru Kosaka; Ryotaro Matsuda; Akihiro Hori; Yuh Hijikata; Rodion V Belosludov; Shigeyoshi Sakaki; Masaki Takata; Susumu Kitagawa
Journal:  Science       Date:  2013-12-12       Impact factor: 47.728

6.  Short Enantioselective Total Synthesis of (-)-Rhazinilam Using a Gold(I)-Catalyzed Cyclization.

Authors:  Valentin Magné; Charlotte Lorton; Angela Marinetti; Xavier Guinchard; Arnaud Voituriez
Journal:  Org Lett       Date:  2017-09-06       Impact factor: 6.005

7.  Thermochromic organometallic complexes: experimental and theoretical studies of 16- to 18-electron interconversions of adducts of arene Ru(II) carboranes with aromatic amine ligands.

Authors:  Nicolas P E Barry; Robert J Deeth; Guy J Clarkson; Ivan Prokes; Peter J Sadler
Journal:  Dalton Trans       Date:  2012-12-06       Impact factor: 4.390

8.  Pd-Catalyzed C(sp2)-H aminocarbonylation using the Langlois reagent as a carbonyl source.

Authors:  Xiao-Fang Li; Lin-Feng Shi; Xing-Guo Zhang; Xiao-Hong Zhang
Journal:  Org Biomol Chem       Date:  2018-09-11       Impact factor: 3.876

9.  Aminocarbonylations employing Mo(CO)6 and a bridged two-vial system: allowing the use of nitro group substituted aryl iodides and aryl bromides.

Authors:  Patrik Nordeman; Luke R Odell; Mats Larhed
Journal:  J Org Chem       Date:  2012-12-12       Impact factor: 4.354

10.  Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts.

Authors:  Nastaran Ranjbar Sahraie; Ulrike I Kramm; Julian Steinberg; Yuanjian Zhang; Arne Thomas; Tobias Reier; Jens-Peter Paraknowitsch; Peter Strasser
Journal:  Nat Commun       Date:  2015-10-21       Impact factor: 14.919
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  1 in total

1.  Anticancer Water-Soluble Organoruthenium Complexes: Synthesis and Preclinical Evaluation.

Authors:  Maria Azmanova; Laia Rafols; Patricia A Cooper; Colin C Seaton; Steven D Shnyder; Anaïs Pitto-Barry
Journal:  Chembiochem       Date:  2022-08-03       Impact factor: 3.461
  1 in total

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