| Literature DB >> 30520891 |
Vera V Butova1, Andriy P Budnyk, Konstantin M Charykov, Kristina S Vetlitsyna-Novikova, Carlo Lamberti, Alexander V Soldatov.
Abstract
We report a careful investigation of a selective phase formation in the zirconium-terephthalic acid system during solvothermal synthesis, which could result in the UiO-66 (Zr6O6(OH)4(BDC)6) or MIL-140A (ZrO(BDC)) metal-organic frameworks (MOFs). The introduction of water varies the phase from MIL-140A to UiO-66 by producing at the nucleation stage tetragonal ZrO2 nanoparticles, where the local arrangement of Zr and O atoms is similar to that in the UiO-66 SBU.Entities:
Year: 2019 PMID: 30520891 DOI: 10.1039/c8cc07709f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222