Amorphous silicon on indium tin oxide: a transparent electrode for simultaneous light activated electrochemistry and optical microscopy.

Herein is reported a new type of transparent electrode, prepared by depositing a thin layer of amorphous silicon film on indium tin oxide, which enables photoswitchable electrochemistry and optical imaging to be performed simultaneously. This offers the opportunity to visualise a spatially controlled electrochemical event on an unstructured electrode surface.