Literature DB >> 30506547

Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis.

Hiroki Haruki1, Shigeo Yasuda1, Kazunori Nagao1, Hirohisa Ohmiya1.   

Abstract

Dehydrative allylation between widely available aldehydes and allylic alcohols to afford β,γ-unsaturated ketones was enabled by a synergistic merger of a thiazolium N-heterocyclic carbene catalyst and a palladium-bisphosphine catalyst.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  aldehyde; carbene; dehydrative allylation; palladium; synergistic catalysis

Year:  2018        PMID： 30506547     DOI： 10.1002/chem.201805955

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  2 in total

1.  Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide.

Authors:  Yangyang Weng; Chenhuan Zhang; Zaiquan Tang; Mohini Shrestha; Wenyi Huang; Jingping Qu; Yifeng Chen
Journal:  Nat Commun       Date:  2020-01-20       Impact factor: 14.919

2.  Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms.

Authors:  Guogang Deng; Shengzu Duan; Jing Wang; Zhuo Chen; Tongqi Liu; Wen Chen; Hongbin Zhang; Xiaodong Yang; Patrick J Walsh
Journal:  Nat Commun       Date:  2021-06-23       Impact factor: 14.919
  2 in total

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