Adsorption behaviors of phenanthrene and bisphenol A in purple paddy soils amended with straw-derived DOM in the West Sichuan Plain of China.

The objectives of this study were to investigate the adsorption and transfer behaviors of phenanthrene (PHE) and bisphenol A (BPA) in purple paddy soils amended with dissolved organic matter (DOM) derived from rice and canola straw in the West Sichuan Plain of China. In the pristine soil, PHE was preferentially adsorbed on both pristine clayey (L) and sandy (T) paddy soils than BPA, indicating that the retention/adsorption by soils is closely dependent on the chemical properties of organic pollutants (OPs). The noticeably higher adsorption of PHE and BPA on smaller size fraction of the soils (L2 and T2) were observed, possibly due to their higher surface areas and higher content in organic matters with higher aromaticity and hydrophobicity in this soil fraction. The DOMs derived from rice (RDOM) and canola (CDOM) straws possessed remarkable differences in E2/E3 and SUV254 measurements, which reflected that their chemical composition might be different. When CDOM was introduced in the studied soil T1, adsorption of BPA was doubled, but the augment in adsorption was much less impressive with RDOM, showing the nature of derived DOM played an important role. The study also demonstrated that in the fine fraction of clayey soil (L2), the retention of a same OP (PHE) was remarkably dropped when CDOM or RDOM was introduced, whereas in a sandy soil of the same size fraction (T2), the phenomenon was the opposite, suggesting a potential risk that, in certain types of soil, the introduction of straw derived DOMs may enhance the mobility of some OPs. The humification time of straw seems not to affect the adsorptions of OPs in most studied systems. Adsorption kinetics of PHE and BPA in the adsorption systems with derived DOMs were well fitted to the two-step first-order model with radj2 values of 0.994-0.998. Results of this study will provide further comprehensive fundamental data for risk assessment and control of organic pollutants (OPs) in farmland ecosystems.