Literature DB >> 30500184

Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex.

Brennan S Billow1, Brooke N Livesay2, Charles C Mokhtarzadeh3, John McCracken1, Matthew P Shores2, James M Boncella3, Aaron L Odom1.   

Abstract

Reduction of IU(NHAriPr6)2 (AriPr6 = 2,6-(2,4,6-iPr3C6H2)2C6H3) results in a rare example of a U(II) complex, U(NHAriPr6)2, and the first example that is a neutral species. Here, we show spectroscopic and magnetic studies that suggest a 5f46d0 valence electronic configuration for uranium, along with characterization of related U(III) complexes.

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Year:  2018        PMID： 30500184     DOI： 10.1021/jacs.8b10888

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  A terminal neptunium(V)-mono(oxo) complex.

Authors:  Michał S Dutkiewicz; Conrad A P Goodwin; Mauro Perfetti; Andrew J Gaunt; Jean-Christophe Griveau; Eric Colineau; Attila Kovács; Ashley J Wooles; Roberto Caciuffo; Olaf Walter; Stephen T Liddle
Journal:  Nat Chem       Date:  2022-02-10       Impact factor: 24.427

2.  Stable Actinide π Complexes of a Neutral 1,4-Diborabenzene.

Authors:  Valerie Paprocki; Peter Hrobárik; Katie L M Harriman; Martin S Luff; Thomas Kupfer; Martin Kaupp; Muralee Murugesu; Holger Braunschweig
Journal:  Angew Chem Int Ed Engl       Date:  2020-05-25       Impact factor: 15.336

3.  Single metal four-electron reduction by U(ii) and masked "U(ii)" compounds.

Authors:  Dieuwertje K Modder; Chad T Palumbo; Iskander Douair; Rosario Scopelliti; Laurent Maron; Marinella Mazzanti
Journal:  Chem Sci       Date:  2021-03-22       Impact factor: 9.825

4.  Redox and structural properties of accessible actinide(ii) metallocalixarenes (Ac to Pu): a relativistic DFT study.

Authors:  Shuai Niu; Hong-Xue Cai; Hong-Bo Zhao; Li Li; Qing-Jiang Pan
Journal:  RSC Adv       Date:  2020-07-17       Impact factor: 3.361

5.  An Allyl Uranium(IV) Sandwich Complex: Are ϕ Bonding Interactions Possible?

Authors:  Ivan A Popov; Brennan S Billow; Stephanie H Carpenter; Enrique R Batista; James M Boncella; Aaron M Tondreau; Ping Yang
Journal:  Chemistry       Date:  2022-04-01       Impact factor: 5.020

6.  Identification of Oxidation State +1 in a Molecular Uranium Complex.

Authors:  Luciano Barluzzi; Sean R Giblin; Akseli Mansikkamäki; Richard A Layfield
Journal:  J Am Chem Soc       Date:  2022-09-28       Impact factor: 16.383

7.  Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states.

Authors:  Justin C Wedal; Jeffrey M Barlow; Joseph W Ziller; Jenny Y Yang; William J Evans
Journal:  Chem Sci       Date:  2021-05-07       Impact factor: 9.825
  7 in total

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