| Literature DB >> 30479048 |
Alex Cartier1, Etienne Levernier2, Vincent Corcé2, Takahide Fukuyama1, Anne-Lise Dhimane2, Cyril Ollivier2, Ilhyong Ryu1,3, Louis Fensterbank2.
Abstract
Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.Entities:
Keywords: carbonylation; photocatalysis; radicals; silicates; three-component reactions
Year: 2019 PMID： 30479048 DOI： 10.1002/anie.201811858
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336