Metal Organic Frameworks (MOFs) and ultrasound: A review.

Metal-organic frameworks (MOFs) have received a lot of attention due to their unique properties and abundant functionalities. Permanent porosity and high surface area are just a few traits that have made them attractive to researchers. They can be prepared as task-specific materials by exploiting the functional group variety and tuning their size and geometry. The main purpose of this review is to present an alternative method of preparing MOF crystals and underline the advantages of ultrasound assisted (sonochemical) synthesis. State of the art ultrasound assisted techniques for the preparation of MOFs in nanoscale are presented. Optimization of morphology and particle size is highlighted throughout this work, as we discuss the effects of various factors, such as energy input, reagent concentration, adequate solvents, reaction time and more.