| Literature DB >> 30474269 |
Meike Niggemann1, Shuang Gao1.
Abstract
Ready for the open waters? Recent developments have fundamentally changed our knowledge of vinyl cation reactivity. The myth that they are too reactive for a predictable reaction design has been debunked, and the applicability of their most distinguished feature, namely their carbene-like reactivity, has taken a major leap forwards. Vinyl cations have thus matured into distinct reactive intermediates with a bright future ahead.Entities:
Keywords: C(sp3)−H functionalization; C−H insertion; carbene analogues; carbocations; vinyl cations
Year: 2018 PMID: 30474269 DOI: 10.1002/anie.201810701
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336