Literature DB >> 30474269

Are Vinyl Cations Finally Coming of Age?

Meike Niggemann1, Shuang Gao1.   

Abstract

Ready for the open waters? Recent developments have fundamentally changed our knowledge of vinyl cation reactivity. The myth that they are too reactive for a predictable reaction design has been debunked, and the applicability of their most distinguished feature, namely their carbene-like reactivity, has taken a major leap forwards. Vinyl cations have thus matured into distinct reactive intermediates with a bright future ahead.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C(sp3)−H functionalization; C−H insertion; carbene analogues; carbocations; vinyl cations

Year:  2018        PMID: 30474269     DOI: 10.1002/anie.201810701

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  5 in total

1.  Substituted α-Alkylidene Cyclopentenones via the Intramolecular Reaction of Vinyl Cations with Alkenes.

Authors:  Magenta J Hensinger; Nicholas J Dodge; Matthias Brewer
Journal:  Org Lett       Date:  2019-12-24       Impact factor: 6.005

2.  Migratory Aptitudes in Rearrangements of Destabilized Vinyl Cations.

Authors:  Sarah E Cleary; Magenta J Hensinger; Zhi-Xin Qin; Xin Hong; Matthias Brewer
Journal:  J Org Chem       Date:  2019-11-20       Impact factor: 4.354

3.  Electrochemical Fluorination of Vinyl Boronates through Donor-Stabilized Vinyl Carbocation Intermediates.

Authors:  Benjamin Wigman; Woojin Lee; Wenjing Wei; Kendall N Houk; Hosea M Nelson
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-03       Impact factor: 15.336

4.  Stereodivergent Alkyne Hydrofluorination Using Protic Tetrafluoroborates as Tunable Reagents.

Authors:  Rui Guo; Xiaotian Qi; Hengye Xiang; Paul Geaneotes; Ruihan Wang; Peng Liu; Yi-Ming Wang
Journal:  Angew Chem Int Ed Engl       Date:  2020-07-14       Impact factor: 15.336

5.  IR-Spectroscopic and X-ray-Structural Study of Vinyl-Type Carbocations in Their Carborane Salts.

Authors:  Evgenii S Stoyanov; Irina Yu Bagryanskaya; Irina V Stoyanova
Journal:  ACS Omega       Date:  2022-07-29
  5 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.