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Literature DB >> 30444958

The Quest for Stable Silaaldehydes: Synthesis and Reactivity of a Masked Silacarbonyl.

Debotra Sarkar¹, Vitaly Nesterov¹, Tibor Szilvási², Philipp J Altmann¹, Shigeyoshi Inoue¹.

Abstract

The first donor-acceptor complex of a silaaldehyde, with the general formula (NHC)(Ar)Si(H)OGaCl3 (NHC=N-heterocyclic carbene), was synthesized using the reaction of silyliumylidene-NHC complex [(NHC)2 (Ar)Si]Cl with water in the presence of GaCl3 . Conversion of this complex to the corresponding silacarboxylate dimer [(NHC)(Ar)SiO2 GaCl2 ]2 , free silaacetal ArSi(H)(OR)2 , silaacyl chloride (NHC)(Ar)Si(Cl)OGaCl3 , and phosphasilene-NHC adduct (NHC)(Ar)Si(H)PTMS unveil its true potential as a synthon in silacarbonyl chemistry.

Entities: Chemical Disease Species

Keywords: N-heterocyclic carbenes; silaaldehydes; silacarbonyl groups; silanones; silyliumylidenes

Year: 2018 PMID： 30444958 DOI： 10.1002/chem.201805604

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

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Cited

4 in total

1. Facile Access to Dative, Single, and Double Silicon-Metal Bonds Through M-Cl Insertion Reactions of Base-Stabilized Si^II Cations.

Authors: Philipp Frisch; Tibor Szilvási; Shigeyoshi Inoue
Journal: Chemistry Date: 2020-04-28 Impact factor: 5.236

The Quest for Stable Silaaldehydes: Synthesis and Reactivity of a Masked Silacarbonyl.

1. Facile Access to Dative, Single, and Double Silicon-Metal Bonds Through M-Cl Insertion Reactions of Base-Stabilized Si^II Cations.

2. An Isolable Bis(Silanone-Borane) Adduct.

Review 3. Acid-Base Free Main Group Carbonyl Analogues.

Review 4. Main Group Multiple Bonds for Bond Activations and Catalysis.

The Quest for Stable Silaaldehydes: Synthesis and Reactivity of a Masked Silacarbonyl.

1. Facile Access to Dative, Single, and Double Silicon-Metal Bonds Through M-Cl Insertion Reactions of Base-Stabilized SiII Cations.

2. An Isolable Bis(Silanone-Borane) Adduct.

Review 3. Acid-Base Free Main Group Carbonyl Analogues.

Review 4. Main Group Multiple Bonds for Bond Activations and Catalysis.

1. Facile Access to Dative, Single, and Double Silicon-Metal Bonds Through M-Cl Insertion Reactions of Base-Stabilized Si^II Cations.