The reuse of waste glass for enhancement of heavy metals immobilization during the introduction of galvanized sludge in brick manufacturing.

The mixing of galvanized sludge in fired clay brick manufacturing has been regarded as an alternative approach for the consumption of galvanized sludge. Decreasing the surface area and porosity of fired brick definitely lowers the risk of heavy metal release. In this study, a novel method is proposed to reduce the surface area and porosity of bricks and promote heavy metal immobilization by adding waste glass. The introduction of waste glass enhanced the physical and mechanical performances of fired clay bricks and resulted in an increase in bulk density and compressive strength and a decrease in water absorption. Microstructure analysis showed that the texture of the bricks turned from porous to smooth and homogeneous due to the introduction of waste glass. Porosity analysis showed that surface area and pore volume of fired brick were substantially reduced. When the added waste glass amount exceeded 15 wt%, the heavy metal concentrations that leached from bricks containing 10 wt% galvanized sludge fired at 950 °C met the regulatory requirement. These results demonstrate that waste glass can be reused to enhance the stabilization/solidification of heavy metals, during the mixing of hazardous waste in bricks and ceramics manufacturing process.