| Literature DB >> 30397992 |
Andrew G Dalling1, Takayuki Yamauchi1, Niall G McCreanor1, Lydia Cox1, John F Bower1.
Abstract
Rh-catalyzed carbonylative C-C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions. These studies provide the first examples of multicomponent cycloadditions that proceed through C-C bond activation of "simple" electron poor cyclopropanes.Entities:
Keywords: C−C activation; cycloaddition; cyclopropane; rhodium
Year: 2018 PMID： 30397992 DOI： 10.1002/anie.201811460
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336