Literature DB >> 30394755

Benzyne Insertion onto β-Keto Esters of Polycyclic Natural Products: Synthesis of Benzo Octacyclo Scaffolds.

Shivakrishna Kallepu1, Karekar Sanjeev1,2, Rambabu Chegondi1,2, Prathama S Mainkar1,2, Srivari Chandrasekhar1,2.   

Abstract

Benzyne insertion to build the privileged scaffold of a [6.8.6]-tricyclic framework on polycyclic and sp3-rich natural products has been developed. The formation of the [6.8.6]-tricyclic ring system is solvent dependent.

Entities:  

Year:  2018        PMID： 30394755     DOI： 10.1021/acs.orglett.8b03070

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  1 in total

1.  H-Bond Mediated Phase-Transfer Catalysis: Enantioselective Generating of Quaternary Stereogenic Centers in β-Keto Esters.

Authors:  Patryk Niedbała; Maciej Majdecki; Piotr Grodek; Janusz Jurczak
Journal:  Molecules       Date:  2022-04-13       Impact factor: 4.927
  1 in total

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