| Literature DB >> 30392358 |
Ayumi Watanabe1, Kazunori Miyamoto1, Tomohide Okada2, Tomotake Asawa2, Masanobu Uchiyama1,3.
Abstract
A practical method for the preparation of (diacetoxyiodo)arene ArI(OAc)2 is described. The use of commercially available sodium hypochlorite pentahydrate (NaClO·5H2O) enabled safe, rapid, and inexpensive oxidation of iodoarenes with electron-withdrawing and -donating substituents. The method allows tandem divergent access to synthetically useful organo-λ3-iodanes such as hydroxyl(tosyloxy)iodobenzene, iodosylbenzene, iodonium ylide, etc.Entities:
Year: 2018 PMID： 30392358 DOI： 10.1021/acs.joc.8b02541
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354