| Literature DB >> 30381222 |
Zhongquan Xin1, Shasha Ma1, Dabing Ren1, Wenbin Liu1, Binsong Han1, Yi Zhang2, Jianbo Xiao3, Lunzhao Yi4, Baichuan Deng5.
Abstract
Multi-components of green tea from different origins were identified by UPLC-Orbitrap-MS/MS, including alkaloids, amino acids, catechins, flavones, flavone glycosides, phenolic acids and theaflavins. Quantitative chemical profiles of 72 samples of Yunnan green tea (YGT) and Hunan green tea (HGT) established the influence of origin on green tea. In addition, three variable selection methods, based on partial least squares-discriminant analysis (PLS-DA), were employed to screen characteristic components of YGT and HGT. The results of variable importance on projection (VIP) method showed better performance than coefficients β and the least absolute shrinkage and selection operator (LASSO) for this dataset. Three characteristic components, named, gallocatechin gallate (GCG), epicatechin-(4β → 8)-epigallocatechin-3-O-gallate, and vitexin were selected by VIP, with a correct rate of 98.61% and an AUC value of 0.9706. The results indicated that the combination of UPLC-Orbitrap-MS/MS and chemometrics could serve as a valid strategy to analyze complex analytical objects, such as green tea.Entities:
Keywords: 1,4,6-Trigalloyl-β-d-glucopyranose (PubChem CID: 14284610); Chemometrics; Epicatechin gallate (PubChem CID: 107905); Gallocatechin gallate (PubChem CID: 199472); Green tea; Kaempferol 3-O-glucoside (PubChem CID: 5282102); Quantitative chemical profile; Theaflavin (PubChem CID: 114777); Theaflavin 3,3′-digallate (PubChem CID: 58252602); Theaflavin 3-gallate (PubChem CID: 102115506); Theaflavin 3′-gallate (PubChem CID: 467321); Tryptophan (PubChem CID: 6305); UPLC–Orbitrap–MS/MS; Vitexin (PubChem CID: 5280441)
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Year: 2018 PMID： 30381222 DOI： 10.1016/j.foodchem.2018.06.056
Source DB: PubMed Journal: Food Chem ISSN： 0308-8146 Impact factor: 7.514