Giant Microgels with CO2-Induced On-Off, Selective, and Recyclable Adsorption for Anionic Dyes.

Adsorbents that are capable of controllable pollutants adsorption and release without secondary pollution are attractive in water treatment. Here, we propose eco-friendly CO2 as a trigger to switch the charge states and collapse-expansion transition of giant microgels consisting of hydrophilic acrylamide and hydrophobic 2-(diethylamino)ethyl methacrylate and demonstrated the on-off, selective, and recyclable adsorption of anionic dyes on microgels under CO2 stimulation. Apart from easy-handling separation from the water by a simple filtration process, the maximum adsorption capacity is as high as 821 mg g-1, and the adsorption isotherms and kinetics obeyed Langmuir isotherm and the pseudo-second-order kinetics models, respectively. The anionic dye can also be separated from the mixture solution using CO2-treated microgels. Moreover, a wastewater treatment prototype with microgel-packed column was fabricated. Under continuous flow condition, the dye was removed and recovered by alternative bubbling CO2 and flushing with aqueous alkali (pH 12). Thus, this type of microgels with CO2-induced protonation-deprotonation transition can serve as a cost-effective, environmentally friendly, and efficient adsorbent for water purification applications.