Literature DB >> 30357178

Coinage metal complexes of NHC-stabilized silyliumylidene ions.

Philipp Frisch1, Shigeyoshi Inoue.   

Abstract

The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

Entities:  

Year:  2018        PMID： 30357178     DOI： 10.1039/c8cc07754a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Facile Access to Dative, Single, and Double Silicon-Metal Bonds Through M-Cl Insertion Reactions of Base-Stabilized SiII Cations.

Authors:  Philipp Frisch; Tibor Szilvási; Shigeyoshi Inoue
Journal:  Chemistry       Date:  2020-04-28       Impact factor: 5.236

2.  Dehydrogenative Double C-H Bond Activation in a Germylene-Rhodium Complex*.

Authors:  Sonia Bajo; María M Alcaide; Joaquín López-Serrano; Jesús Campos
Journal:  Chemistry       Date:  2021-10-27       Impact factor: 5.020
  2 in total

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