Literature DB >> 30345441

Generation and conversion of an N-heterocyclic carbene on Pt(111).

Yang Zeng1, Tianchi Zhang1, Mina R Narouz2, Cathleen M Crudden3, Peter H McBreen1.   

Abstract

The formation of N-heterocyclic carbenes on a platinum surface is demonstrated. Surface vibrational spectroscopy measurements isolate steps in the transformation from 1,3-diisopropylbenzimidazolium hydrogen carbonate to surface carbene. As the temperature is further increased, the reactive metal transforms the isopropyl groups leading to the effective formation of a new surface carbene.

Entities:  

Year:  2018        PMID： 30345441     DOI： 10.1039/c8cc06894a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Highly Ordered N-Heterocyclic Carbene Monolayers on Cu(111).

Authors:  Eloise Angove; Federico Grillo; Herbert A Früchtl; Alex J Veinot; Ishwar Singh; J Hugh Horton; Cathleen M Crudden; Christopher J Baddeley
Journal:  J Phys Chem Lett       Date:  2022-02-24       Impact factor: 6.475

2.  Growth of N-Heterocyclic Carbene Assemblies on Cu(100) and Cu(111): From Single Molecules to Magic-Number Islands.

Authors:  Juan J Navarro; Mowpriya Das; Sergio Tosoni; Felix Landwehr; Maximilian Koy; Markus Heyde; Gianfranco Pacchioni; Frank Glorius; Beatriz Roldan Cuenya
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-10       Impact factor: 16.823

3.  Self-assembly of N-heterocyclic carbenes on Au(111).

Authors:  Alex Inayeh; Ryan R K Groome; Ishwar Singh; Alex J Veinot; Felipe Crasto de Lima; Roberto H Miwa; Cathleen M Crudden; Alastair B McLean
Journal:  Nat Commun       Date:  2021-06-29       Impact factor: 14.919
  3 in total

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