Literature DB >> 30328242

The Curious Case of Ketene in Zeolite Chemistry and Catalysis.

Abhishek Dutta Chowdhury1, Jorge Gascon1.   

Abstract

Ketenes in the limelight: The influential role of ketenes has never been adequately acknowledged in zeolite chemistry and catalysis; unlike other first generation highly reactive intermediates, such as carbocations, carbanions, radicals, and carbenes. In fact, the role that ketenes play during catalysis-whether beneficial or detrimental-is a contentious subject that requires further consideration.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  heterogeneous catalysis; ketenes; reaction mechanisms; spectroscopy; zeolites

Year:  2018        PMID: 30328242     DOI: 10.1002/anie.201808480

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  4 in total

1.  Elucidation of radical- and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons.

Authors:  Alessia Cesarini; Sharon Mitchell; Guido Zichittella; Mikhail Agrachev; Stefan P Schmid; Gunnar Jeschke; Zeyou Pan; Andras Bodi; Patrick Hemberger; Javier Pérez-Ramírez
Journal:  Nat Catal       Date:  2022-06-27

2.  On the absolute photoionization cross section and threshold photoelectron spectrum of two reactive ketenes in lignin valorization: fulvenone and 2-carbonyl cyclohexadienone.

Authors:  Zeyou Pan; Andras Bodi; Jeroen A van Bokhoven; Patrick Hemberger
Journal:  Phys Chem Chem Phys       Date:  2022-02-09       Impact factor: 3.676

3.  Surface enhanced dynamic nuclear polarization solid-state NMR spectroscopy sheds light on Brønsted-Lewis acid synergy during the zeolite catalyzed methanol-to-hydrocarbon process.

Authors:  Abhishek Dutta Chowdhury; Irina Yarulina; Edy Abou-Hamad; Andrei Gurinov; Jorge Gascon
Journal:  Chem Sci       Date:  2019-08-21       Impact factor: 9.825

4.  Molecular Understanding of the Catalytic Consequence of Ketene Intermediates under Confinement.

Authors:  Wei Chen; Guangchao Li; Xianfeng Yi; Sarah J Day; Karolina A Tarach; Zhiqiang Liu; Shang-Bin Liu; Shik Chi Edman Tsang; Kinga Góra-Marek; Anmin Zheng
Journal:  J Am Chem Soc       Date:  2021-09-03       Impact factor: 15.419

  4 in total

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